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Chemistry

A Cleaner Future for Tires: Scientists Pioneer Chemical Process to Repurpose Rubber Waste

Every year, millions of tires end up in landfills, creating an environmental crisis with far-reaching consequences. In the United States alone, over 274 million tires were scrapped in 2021, with nearly a fifth of them being discarded into landfills. A study has now pioneered a technique for breaking down this rubber waste and transforming it into valuable precursors for epoxy resins. This technique offers an innovative and sustainable alternative to traditional recycling methods while significantly reducing rubber waste in landfills.

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A staggering 274 million tires were discarded in the United States alone in 2021, with nearly a fifth of them ending up in landfills. The environmental crisis posed by these waste materials is far-reaching and devastating. While traditional recycling methods like pyrolysis can break down rubber through high-temperature decomposition, they generate harmful byproducts like benzene and dioxins, posing serious health and environmental risks.

A groundbreaking study published in Nature has introduced a novel chemical method for breaking down rubber waste. Led by Dr. Aleksandr Zhukhovitskiy, this pioneering technique utilizes C-H amination and a polymer rearrangement strategy to transform discarded rubber into valuable precursors for epoxy resins. This innovative approach offers an efficient and sustainable alternative to traditional recycling methods.

The researchers’ method involves installing amine groups at specific locations in the polymer chains using a sulfur diimide reagent. This step sets the stage for the subsequent backbone rearrangement, which breaks down the rubber into soluble amine-functionalized materials that can be used to produce epoxy resins. The efficiency of this process is striking when compared to traditional recycling techniques, which often require extreme temperatures or expensive catalysts.

In a test with a model polymer, the researchers achieved a significant reduction in molecular weight from 58,100 g/mol to about 400 g/mol. When applied to used rubber, their method broke down the material completely in just six hours, turning it into a soluble material with amine groups that can be used to manufacture broadly useful materials like epoxy resins.

Epoxy resins are widely used in industries for adhesives, coatings, and composites. They are usually made from petroleum-based chemicals like bisphenol A and curing agents. This research shows that amine-modified poly-dienes, produced using the researchers’ method, can create epoxy materials with strength similar to commercial resins.

The study marks a significant step toward greener recycling technologies. The researchers evaluated the environmental impact of their process using the Environmental Impact Factor (E-factor), which highlights areas where the process could be further optimized for sustainability. While the complete E-factor was high, the simple E-factor, excluding solvents, was much lower, indicating potential avenues for improvement.

The team is already exploring greener solvent systems and alternative reaction conditions to reduce waste generation. This research represents a paradigm shift in how we approach the problem of rubber waste, providing a new pathway to transforming post-consumer rubber into high-value materials that minimize environmental harm.

Chemistry

Scientists Confirm a Fundamental Quantum Rule for the First Time

Scientists have, for the first time, experimentally proven that angular momentum is conserved even when a single photon splits into two, pushing quantum physics to its most fundamental limits. Using ultra-precise equipment, the team captured this elusive process—comparable to finding a needle in a haystack—confirming a cornerstone law of nature at the photon level.

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Scientists at Tampere University and their international collaborators have made a groundbreaking discovery in the field of quantum physics. They have experimentally confirmed that angular momentum is conserved when a single photon is converted into a pair, validating a key principle of physics at the quantum level for the first time. This breakthrough has significant implications for creating complex quantum states useful in computing, communication, and sensing.

In essence, the researchers have tested the conservation laws of rotating objects to see if they also apply to light. They found that when a photon with zero orbital angular momentum is split into two photons, the OAM quanta of both photons must add to zero. This means that if one of the newly generated photons has one OAM quanta, its partner photon must have the opposite, i.e., negative OAM quanta.

The researchers used an extremely stable optical setup and delicate measurements to record enough successful conversions such that they could confirm the fundamental conservation law. They also observed first indications of quantum entanglement in the generated photon pairs, which suggests that the technique can be extended to create more complex photonic quantum states.

This work is not only of fundamental importance but also takes us a significant step closer to generating novel quantum states, where the photons are entangled in all possible ways. The researchers plan to improve the overall efficiency of their scheme and develop better strategies for measuring the generated quantum state such that in the future these photonic needles can be found easier in the laboratory haystack.

The confirmation of this fundamental quantum rule opens new possibilities for creating complex quantum states useful in computing, communication, and sensing. It also takes us a significant step closer to generating novel quantum states, where the photons are entangled in all possible ways, i.e., in space, time, and polarization.

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Biochemistry

Scientists Finally Tame the Impossible: A Stable 48-Atom Carbon Ring is Achieved

Researchers have synthesized a stable cyclo[48]carbon, a unique 48-carbon ring that can be studied in solution at room temperature, a feat never achieved before.

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The discovery of a new type of molecular carbon allotrope, known as cyclocarbon, has been a long-standing challenge for chemists. A team of researchers from Oxford University’s Department of Chemistry, led by Dr Yueze Gao and senior author Professor Harry Andersen, have successfully synthesized a stable 48-atom carbon ring in solution at room temperature. This achievement marks a significant breakthrough in the field, as previous attempts to study cyclocarbons were limited to the gas phase or extremely low temperatures (4 to 10 K).

The researchers employed a unique approach by synthesizing a cyclocarbon catenane, where the C48 ring is threaded through three other macrocycles. This design increases the stability of the molecule, preventing access to the sensitive cyclocarbon core. The team developed mild reaction conditions for the unmasking step in the synthesis process, which allowed them to achieve a stable cyclocarbon in solution at 20°C.

The cyclocarbon catenane was characterized using various spectroscopic techniques, including mass spectrometry, NMR, UV-visible, and Raman spectroscopy. The observation of a single intense 13C NMR resonance for all 48 sp1 carbon atoms provides strong evidence for the cyclocarbon catenane structure.

Lead author Dr Yueze Gao stated that achieving stable cyclocarbons in a vial at ambient conditions is a fundamental step, making it easier to study their reactivity and properties under normal laboratory conditions. Senior author Professor Harry Andersen added that this achievement marks the culmination of a long endeavor, with the original grant proposal written in 2016 based on preliminary results from 2012-2015.

The study also involved researchers from the University of Manchester, the University of Bristol, and the Central Laser Facility, Rutherford Appleton Laboratory. This collaborative effort demonstrates the power of interdisciplinary research in advancing our understanding of complex molecular systems.

This achievement has significant implications for future studies on cyclocarbons and their potential applications in various fields. The researchers’ innovative approach to synthesizing stable cyclocarbons at room temperature opens up new possibilities for exploring the properties and reactivity of these intriguing molecules.

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Chemistry

Scientists Stunned by Record-Breaking, Watermelon-Shaped Nucleus: Breakthrough Discovery in Nuclear Physics

Scientists in Finland have measured the heaviest known nucleus to undergo proton emission, discovering the rare isotope 188-astatine. It exhibits a unique shape and may reveal a new kind of nuclear interaction.

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Scientists have made a groundbreaking discovery in nuclear physics, measuring the heaviest nucleus ever recorded to decay via proton emission. This achievement marks the first time such a feat has been accomplished in over 30 years, with the previous record set in 1996.

The research team from the University of Jyväskylä, Finland, successfully produced and measured the lightest known isotope of astatine, 188At, consisting of 85 protons and 103 neutrons. This exotic nucleus was created through a complex process involving a fusion-evaporation reaction and identified using a sophisticated detector setup.

“The properties of this nucleus reveal a trend change in the binding energy of the valence proton,” explains Doctoral Researcher Henna Kokkonen, who led the study. “This could be explained by an interaction unprecedented in heavy nuclei.”

The research team’s findings have significant implications for our understanding of atomic nuclei and their behavior. By expanding a theoretical model to interpret the measured data, scientists can now better comprehend the intricate mechanisms governing these complex systems.

Kokkonen notes that studying such exotic nuclei is extremely challenging due to their short lifetimes and low production cross sections. However, precise techniques like those employed in this study have made it possible to unlock new insights into the fundamental nature of matter.

The research article was published in Nature Communications as part of an international collaboration involving experts in theoretical nuclear physics. This breakthrough discovery not only pushes the boundaries of human knowledge but also has far-reaching implications for our understanding of the universe and its mysteries.

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