The world’s oldest synthetic pigment, Egyptian blue, has been recreated by a team of researchers from Washington State University. This breakthrough, published in the journal NPJ Heritage Science, provides valuable insights for archaeologists and conservation scientists studying ancient Egyptian materials.

Led by John McCloy, director of WSU’s School of Mechanical and Materials Engineering, the research team collaborated with the Carnegie Museum of Natural History and the Smithsonian’s Museum Conservation Institute to develop 12 recipes for the pigment. These recipes utilized a variety of raw materials and heating times, replicating temperatures available to ancient artists.

Egyptian blue was highly valued in ancient times due to its unique properties and versatility. It was used as a substitute for expensive minerals like turquoise or lapis lazuli and applied to wood, stone, and cartonnage – a papier-mâché-type material. Depending on its ingredients and processing time, the pigment’s color ranged from deep blue to dull gray or green.

The researchers’ work aimed to highlight how modern science can reveal hidden stories in ancient Egyptian objects. After the Egyptians, the pigment was used by Romans, but by the Renaissance period, the knowledge of how it was made had largely been forgotten.

In recent years, there has been a resurgence of interest in Egyptian blue due to its intriguing properties and potential new technological applications. The pigment emits light in the near-infrared part of the electromagnetic spectrum, which people can’t see, making it suitable for fingerprinting and counterfeit-proof inks. It also shares similar chemistry with high-temperature superconductors.

To understand the makeup of Egyptian blue, the researchers created 12 different recipes using mixtures of silicon dioxide, copper, calcium, and sodium carbonate. They heated the material at around 1000 degrees Celsius for between one and 11 hours to replicate temperatures available to ancient artists. After cooling the samples at various rates, they studied the pigments using modern microscopy and analysis techniques that had never been used for this type of research.

The researchers found that Egyptian blue is highly heterogeneous, with different people making the pigment and transporting it to final uses elsewhere. Small differences in the process resulted in very different outcomes. In fact, to get the bluest color required only about 50% of the blue-colored components, regardless of the rest of the mixture’s composition.

The samples created are currently on display at Carnegie Museum of Natural History in Pittsburgh, Pennsylvania and will become part of the museum’s new long-term gallery focused on ancient Egypt. This research serves as a prime example of how science can shed light on our human past, revealing hidden stories in ancient objects and materials.

With the world’s population growing at an unprecedented rate, urban expansion has reached new heights, putting immense pressure on natural resources and the environment. The construction industry, in particular, is facing significant challenges in reducing its carbon footprint while meeting the demand for infrastructure development.

Ordinary Portland Cement (OPC) remains a cornerstone of modern-day infrastructure, despite being a major contributor to global carbon emissions. To address this issue, scientists from Japan have developed a game-changing solution: a high-performance geopolymer-based soil solidifier made from Siding Cut Powder (SCP), a construction waste byproduct, and Earth Silica (ES), sourced from recycled glass.

This breakthrough innovation offers an alternative to reducing cement dependence while transforming construction waste into valuable construction resources. The combination of SCP and ES forms a geopolymer-based solidifier capable of enhancing soil-compressive strength beyond construction-grade thresholds of 160 kN/m2.

The thermal treatment process, which involves heating SCP at 110 °C and 200 °C, significantly improves its reactivity and reduces material use without sacrificing performance. This solution not only meets industry standards but also helps address the dual challenges of construction waste and carbon emissions.

A noteworthy aspect of this research is the approach to environmental safety. Initially, concerns were raised regarding arsenic leaching from recycled glass content in ES. However, scientists demonstrated that incorporating calcium hydroxide effectively mitigated this issue through the formation of stable calcium arsenate compounds, ensuring full environmental compliance.

The implications of this solution are vast and far-reaching. In urban infrastructure development, it can stabilize weak soils beneath roads, buildings, and bridges without relying on carbon-intensive Portland cement. This is particularly valuable in areas with problematic clay soils where conventional stabilization methods are costly and environmentally burdensome.

Disaster-prone regions could benefit from rapid soil stabilization using these materials, which have demonstrated good workability and setting times compatible with emergency response needs. Additionally, rural infrastructure projects in developing regions could utilize these materials to create stabilized soil blocks for construction, providing a low-carbon alternative to fired bricks or concrete.

The geopolymer solidifier offers numerous practical applications across industries. For the construction sector, which faces increasing pressure to decarbonize, this solution provides an alternative that exceeds traditional methods without heavy carbon footprints. For geotechnical engineering firms, its proven durability under sulfate attack, chloride ingress, and freeze-thaw cycles allow its use in demanding and aggressive environments.

By lowering Portland cement usage, this technology supports construction projects aiming to meet green building certifications and carbon reduction targets. It may also allow developers to qualify for environmental incentives in countries where carbon pricing mechanisms are in place, further enhancing its economic viability.

The vision behind this work is broader than just developing a sustainable engineering solution – it’s redefining how we value industrial byproducts in a resource-constrained world. These findings point to a transformative shift in sustainable construction practices, potentially transforming millions of tons of construction waste into valuable resources while reducing the carbon footprint associated with cement production.

The field of materials science has taken a significant leap forward with the creation of designer hybrid 2D materials. A team of researchers from Rice University has successfully synthesized glaphene, a genuine 2D hybrid material by chemically integrating graphene and silica glass into a single compound. This breakthrough discovery opens up new avenues for developing custom-built materials for next-generation electronics, photonics, and quantum devices.

The team employed a two-step, single-reaction method to grow glaphene using a liquid chemical precursor containing both silicon and carbon. By adjusting oxygen levels during heating, they first grew graphene and then shifted conditions to favor the formation of a silica layer. This novel approach allowed them to create a true hybrid material with new electronic and structural properties.

One of the key findings was that the layers in glaphene do not simply rest on each other; instead, electrons move and form new interactions and vibration states, giving rise to properties neither material has on its own. This unique bonding between the graphene and silica layers changes the material’s structure and behavior, turning a metal and an insulator into a new type of semiconductor.

The researchers used various techniques, including Raman spectroscopy and quantum simulations, to verify the experimental results and gain insights into the atomic-level interactions within glaphene. The findings suggest that this hybrid bonding allows electrons to flow between the layers, creating entirely new behaviors.

This research has significant implications for the development of next-generation materials with tailored properties. By combining fundamentally different 2D materials, researchers can create custom-built materials from scratch, enabling breakthroughs in various fields such as electronics, photonics, and quantum computing.

The team’s work reflects a guiding principle that encourages exploring ideas that others may hesitate to mix. This research demonstrates the power of collaboration and interdisciplinary approaches in driving innovation forward. The findings have been supported by various funding organizations and institutions, highlighting the importance of public-private partnerships in advancing scientific knowledge.

In conclusion, the discovery of glaphene represents a major breakthrough in materials science, offering new possibilities for creating designer hybrid 2D materials with tailored properties. This research has significant implications for various fields, from electronics to quantum computing, and underscores the importance of collaboration and interdisciplinary approaches in driving innovation forward.