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Chemistry

A Cleaner Future for Tires: Scientists Pioneer Chemical Process to Repurpose Rubber Waste

Every year, millions of tires end up in landfills, creating an environmental crisis with far-reaching consequences. In the United States alone, over 274 million tires were scrapped in 2021, with nearly a fifth of them being discarded into landfills. A study has now pioneered a technique for breaking down this rubber waste and transforming it into valuable precursors for epoxy resins. This technique offers an innovative and sustainable alternative to traditional recycling methods while significantly reducing rubber waste in landfills.

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A staggering 274 million tires were discarded in the United States alone in 2021, with nearly a fifth of them ending up in landfills. The environmental crisis posed by these waste materials is far-reaching and devastating. While traditional recycling methods like pyrolysis can break down rubber through high-temperature decomposition, they generate harmful byproducts like benzene and dioxins, posing serious health and environmental risks.

A groundbreaking study published in Nature has introduced a novel chemical method for breaking down rubber waste. Led by Dr. Aleksandr Zhukhovitskiy, this pioneering technique utilizes C-H amination and a polymer rearrangement strategy to transform discarded rubber into valuable precursors for epoxy resins. This innovative approach offers an efficient and sustainable alternative to traditional recycling methods.

The researchers’ method involves installing amine groups at specific locations in the polymer chains using a sulfur diimide reagent. This step sets the stage for the subsequent backbone rearrangement, which breaks down the rubber into soluble amine-functionalized materials that can be used to produce epoxy resins. The efficiency of this process is striking when compared to traditional recycling techniques, which often require extreme temperatures or expensive catalysts.

In a test with a model polymer, the researchers achieved a significant reduction in molecular weight from 58,100 g/mol to about 400 g/mol. When applied to used rubber, their method broke down the material completely in just six hours, turning it into a soluble material with amine groups that can be used to manufacture broadly useful materials like epoxy resins.

Epoxy resins are widely used in industries for adhesives, coatings, and composites. They are usually made from petroleum-based chemicals like bisphenol A and curing agents. This research shows that amine-modified poly-dienes, produced using the researchers’ method, can create epoxy materials with strength similar to commercial resins.

The study marks a significant step toward greener recycling technologies. The researchers evaluated the environmental impact of their process using the Environmental Impact Factor (E-factor), which highlights areas where the process could be further optimized for sustainability. While the complete E-factor was high, the simple E-factor, excluding solvents, was much lower, indicating potential avenues for improvement.

The team is already exploring greener solvent systems and alternative reaction conditions to reduce waste generation. This research represents a paradigm shift in how we approach the problem of rubber waste, providing a new pathway to transforming post-consumer rubber into high-value materials that minimize environmental harm.

Chemistry

Scientists Stunned by Record-Breaking, Watermelon-Shaped Nucleus: Breakthrough Discovery in Nuclear Physics

Scientists in Finland have measured the heaviest known nucleus to undergo proton emission, discovering the rare isotope 188-astatine. It exhibits a unique shape and may reveal a new kind of nuclear interaction.

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Scientists have made a groundbreaking discovery in nuclear physics, measuring the heaviest nucleus ever recorded to decay via proton emission. This achievement marks the first time such a feat has been accomplished in over 30 years, with the previous record set in 1996.

The research team from the University of Jyväskylä, Finland, successfully produced and measured the lightest known isotope of astatine, 188At, consisting of 85 protons and 103 neutrons. This exotic nucleus was created through a complex process involving a fusion-evaporation reaction and identified using a sophisticated detector setup.

“The properties of this nucleus reveal a trend change in the binding energy of the valence proton,” explains Doctoral Researcher Henna Kokkonen, who led the study. “This could be explained by an interaction unprecedented in heavy nuclei.”

The research team’s findings have significant implications for our understanding of atomic nuclei and their behavior. By expanding a theoretical model to interpret the measured data, scientists can now better comprehend the intricate mechanisms governing these complex systems.

Kokkonen notes that studying such exotic nuclei is extremely challenging due to their short lifetimes and low production cross sections. However, precise techniques like those employed in this study have made it possible to unlock new insights into the fundamental nature of matter.

The research article was published in Nature Communications as part of an international collaboration involving experts in theoretical nuclear physics. This breakthrough discovery not only pushes the boundaries of human knowledge but also has far-reaching implications for our understanding of the universe and its mysteries.

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Chemistry

Tiny Gold “Super Atoms” Could Spark a Quantum Revolution

Scientists have found that microscopic gold clusters can act like the world’s most accurate quantum systems, while being far easier to scale up. With tunable spin properties and mass production potential, they could transform quantum computing and sensing.

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As researchers from Penn State and Colorado State have demonstrated, tiny gold “super atoms” could revolutionize the field of quantum computing. These clusters, which have a core of gold surrounded by other molecules called ligands, can mimic the properties of trapped atomic ions in a gas, allowing scientists to take advantage of these spin properties in a system that can be easily scaled up.

The researchers found that gold clusters can exhibit spin polarization, a property that is usually fixed in a material. This means that electrons in the cluster can be aligned with each other, making it possible to maintain their correlation for a longer time and remain accurate for much longer periods. The current state-of-the-art system for high accuracy and low error in quantum information systems involve trapped atomic ions — atoms with an electric charge — in a gaseous state.

The gold clusters, which can be synthesized relatively large amounts at one time, have the key properties needed to carry out spin-based operations. They can mimic the super-positions that are done in the trapped, gas-phase dilute ions, and have been identified as having 19 distinguishable and unique Rydberg-like spin-polarized states.

The researchers determined the spin polarization of the gold clusters using a similar method used with traditional atoms. While one type of gold cluster had 7% spin polarization, a cluster with different ligands approached 40% spin polarization, which is competitive with some of the leading two-dimensional quantum materials.

This research has opened up new possibilities for chemists to use their synthesis skills to design materials with tunable results, and could lead to breakthroughs in quantum computing and other fields. The researchers plan to explore how different structures within the ligands impact spin polarization and how they could be manipulated to fine tune spin properties.

In conclusion, tiny gold “super atoms” have the potential to revolutionize the field of quantum computing and could lead to breakthroughs in various fields.

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Chemistry

From Lead to Gold in a Fraction of a Second at the Large Hadron Collider

At the Large Hadron Collider, scientists from the University of Kansas achieved a fleeting form of modern-day alchemy — turning lead into gold for just a fraction of a second. Using ultra-peripheral collisions, where ions nearly miss but interact through powerful photon exchanges, they managed to knock protons out of nuclei, creating new, short-lived elements. This breakthrough not only grabbed global attention but could help design safer, more advanced particle accelerators of the future.

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The Large Hadron Collider (LHC), a 17-mile particle accelerator buried under the French-Swiss border, has achieved the centuries-old dream of alchemists: transforming lead into gold. However, this accomplishment was not without its limitations – it happened within a fraction of a second. The scientists reported their results in Physical Reviews.

The achievement was made possible by the sophisticated and sensitive detector called ALICE, which is roughly the size of a McMansion. It was scientists from the University of Kansas, working on the ALICE experiment, who developed the technique that tracked “ultra-peripheral” collisions between protons and ions that resulted in gold creation at the LHC.

According to Daniel Tapia Takaki, professor of physics and leader of KU’s group at ALICE, these ultra-peripheral collisions involve near misses between particles. The ions racing around the LHC tunnel are heavy nuclei with many protons, each generating powerful electric fields. When accelerated, these charged ions emit photons – they shine light.

“When you accelerate an electric charge to near light speeds, it starts shining,” Tapia Takaki said. “One ion can shine light that essentially takes a picture of the other. When that light is energetic enough, it can probe deep inside the other nucleus, like a high-energy flashbulb.”

During these ultra-peripheral collisions, surprising interactions can occur, including the creation of gold through photon-photon collisions. These events are incredibly clean, with almost nothing else produced. They contrast with typical collisions where sprays of particles flying everywhere.

However, the ALICE detector and the LHC were designed to collect data on head-on collisions that result in messy sprays of particles. These clean interactions were hard to detect with earlier setups.

Tapia Takaki’s KU co-authors on the paper are graduate student Anna Binoy; graduate student Amrit Gautam; postdoctoral researcher Tommaso Isidori; postdoctoral research assistant Anisa Khatun; and research scientist Nicola Minafra. The KU team at the LHC ALICE experiment plans to continue studying the ultra-peripheral collisions.

Tapia Takaki said that while the creation of gold fascinated the public, the potential of understanding the interactions goes deeper. This light is so energetic, it can knock protons out of the nucleus, sometimes one, sometimes two, three or even four protons. We can see these ejected protons directly with our detectors.

Each proton removed changes the elements: One gives thallium, two gives mercury, three gives gold. These new nuclei are very short-lived, they decay quickly, but not always immediately. Sometimes they travel along the beamline and hit parts of the collider – triggering safety systems.

That’s why this research matters beyond the headlines. With proposals for future colliders even larger than the LHC – some up to 100 kilometers in Europe and China – you need to understand these nuclear byproducts. This ‘alchemy’ may be crucial for designing the next generation of machines.

This work was supported by the U.S. Department of Energy Office of Science, Office of Nuclear Physics.

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