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Chemistry

Mapping Platinum Atoms for a Greener Future in Catalysis

A precious metal used everywhere from car exhaust systems to fuel cells, platinum is an incredibly efficient catalyst—but it’s costly and carbon-intensive. Now, a serendipitous collaboration between scientists at ETH Zurich and other European institutions has opened a new frontier in understanding and optimizing platinum-based catalysts at the atomic level.

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The field of catalysis has revolutionized industries and everyday life, with around 80% of all chemical products relying on this principle. One particularly effective catalyst is platinum, but its rarity and expense make it essential to use it efficiently. Researchers at ETH Zurich have made a groundbreaking discovery by mapping the atomic environments of single platinum atoms in solid supports, paving the way for optimized production of single-atom catalysts.

Using nuclear magnetic resonance (NMR), a team led by Javier Pérez-Ramírez and Christophe Copéret was able to study the individual platinum atoms in detail. This method, typically used for investigating molecules, allowed them to show that the atomic environments of these atoms can have very different properties, influencing their catalytic action.

The researchers found that each platinum atom has a unique combination of neighboring atoms and spatial orientation, similar to the distinct tones in an orchestra. By developing a computer code with the help of a simulation expert, they were able to filter out the different “tones” and create a map of the atomic environments surrounding the platinum atoms.

This breakthrough enables the optimization of production protocols for single-atom catalysts, where all platinum atoms can have tailored environments. The researchers aim to develop more efficient catalytic materials, which is crucial for a greener future in industries such as fuel cells and exhaust catalysts.

The discovery has significant intellectual property implications, allowing the precise description of catalysts at the atomic level and enabling patent protection. This innovation has far-reaching consequences for the development of more sustainable technologies and could transform the field of catalysis forever.

Chemistry

Scientists Confirm a Fundamental Quantum Rule for the First Time

Scientists have, for the first time, experimentally proven that angular momentum is conserved even when a single photon splits into two, pushing quantum physics to its most fundamental limits. Using ultra-precise equipment, the team captured this elusive process—comparable to finding a needle in a haystack—confirming a cornerstone law of nature at the photon level.

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Scientists at Tampere University and their international collaborators have made a groundbreaking discovery in the field of quantum physics. They have experimentally confirmed that angular momentum is conserved when a single photon is converted into a pair, validating a key principle of physics at the quantum level for the first time. This breakthrough has significant implications for creating complex quantum states useful in computing, communication, and sensing.

In essence, the researchers have tested the conservation laws of rotating objects to see if they also apply to light. They found that when a photon with zero orbital angular momentum is split into two photons, the OAM quanta of both photons must add to zero. This means that if one of the newly generated photons has one OAM quanta, its partner photon must have the opposite, i.e., negative OAM quanta.

The researchers used an extremely stable optical setup and delicate measurements to record enough successful conversions such that they could confirm the fundamental conservation law. They also observed first indications of quantum entanglement in the generated photon pairs, which suggests that the technique can be extended to create more complex photonic quantum states.

This work is not only of fundamental importance but also takes us a significant step closer to generating novel quantum states, where the photons are entangled in all possible ways. The researchers plan to improve the overall efficiency of their scheme and develop better strategies for measuring the generated quantum state such that in the future these photonic needles can be found easier in the laboratory haystack.

The confirmation of this fundamental quantum rule opens new possibilities for creating complex quantum states useful in computing, communication, and sensing. It also takes us a significant step closer to generating novel quantum states, where the photons are entangled in all possible ways, i.e., in space, time, and polarization.

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Biochemistry

Scientists Finally Tame the Impossible: A Stable 48-Atom Carbon Ring is Achieved

Researchers have synthesized a stable cyclo[48]carbon, a unique 48-carbon ring that can be studied in solution at room temperature, a feat never achieved before.

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The discovery of a new type of molecular carbon allotrope, known as cyclocarbon, has been a long-standing challenge for chemists. A team of researchers from Oxford University’s Department of Chemistry, led by Dr Yueze Gao and senior author Professor Harry Andersen, have successfully synthesized a stable 48-atom carbon ring in solution at room temperature. This achievement marks a significant breakthrough in the field, as previous attempts to study cyclocarbons were limited to the gas phase or extremely low temperatures (4 to 10 K).

The researchers employed a unique approach by synthesizing a cyclocarbon catenane, where the C48 ring is threaded through three other macrocycles. This design increases the stability of the molecule, preventing access to the sensitive cyclocarbon core. The team developed mild reaction conditions for the unmasking step in the synthesis process, which allowed them to achieve a stable cyclocarbon in solution at 20°C.

The cyclocarbon catenane was characterized using various spectroscopic techniques, including mass spectrometry, NMR, UV-visible, and Raman spectroscopy. The observation of a single intense 13C NMR resonance for all 48 sp1 carbon atoms provides strong evidence for the cyclocarbon catenane structure.

Lead author Dr Yueze Gao stated that achieving stable cyclocarbons in a vial at ambient conditions is a fundamental step, making it easier to study their reactivity and properties under normal laboratory conditions. Senior author Professor Harry Andersen added that this achievement marks the culmination of a long endeavor, with the original grant proposal written in 2016 based on preliminary results from 2012-2015.

The study also involved researchers from the University of Manchester, the University of Bristol, and the Central Laser Facility, Rutherford Appleton Laboratory. This collaborative effort demonstrates the power of interdisciplinary research in advancing our understanding of complex molecular systems.

This achievement has significant implications for future studies on cyclocarbons and their potential applications in various fields. The researchers’ innovative approach to synthesizing stable cyclocarbons at room temperature opens up new possibilities for exploring the properties and reactivity of these intriguing molecules.

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Chemistry

Scientists Stunned by Record-Breaking, Watermelon-Shaped Nucleus: Breakthrough Discovery in Nuclear Physics

Scientists in Finland have measured the heaviest known nucleus to undergo proton emission, discovering the rare isotope 188-astatine. It exhibits a unique shape and may reveal a new kind of nuclear interaction.

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Scientists have made a groundbreaking discovery in nuclear physics, measuring the heaviest nucleus ever recorded to decay via proton emission. This achievement marks the first time such a feat has been accomplished in over 30 years, with the previous record set in 1996.

The research team from the University of Jyväskylä, Finland, successfully produced and measured the lightest known isotope of astatine, 188At, consisting of 85 protons and 103 neutrons. This exotic nucleus was created through a complex process involving a fusion-evaporation reaction and identified using a sophisticated detector setup.

“The properties of this nucleus reveal a trend change in the binding energy of the valence proton,” explains Doctoral Researcher Henna Kokkonen, who led the study. “This could be explained by an interaction unprecedented in heavy nuclei.”

The research team’s findings have significant implications for our understanding of atomic nuclei and their behavior. By expanding a theoretical model to interpret the measured data, scientists can now better comprehend the intricate mechanisms governing these complex systems.

Kokkonen notes that studying such exotic nuclei is extremely challenging due to their short lifetimes and low production cross sections. However, precise techniques like those employed in this study have made it possible to unlock new insights into the fundamental nature of matter.

The research article was published in Nature Communications as part of an international collaboration involving experts in theoretical nuclear physics. This breakthrough discovery not only pushes the boundaries of human knowledge but also has far-reaching implications for our understanding of the universe and its mysteries.

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