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Detectors

Green fabrication of hybrid materials as highly sensitive X-ray detectors: A breakthrough for medical diagnostics and material characterization.

New bismuth-based organic-inorganic hybrid materials show exceptional sensitivity and long-term stability as X-ray detectors, significantly more sensitive than commercial X-ray detectors. In addition, these materials can be produced without solvents by ball milling, a mechanochemical synthesis process that is environmentally friendly and scalable. More sensitive detectors would allow for a reduction in the radiation exposure during X-ray examinations.

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New bismuth-based organic-inorganic hybrid materials have been discovered, showing exceptional sensitivity and long-term stability as X-ray detectors. This breakthrough is set to transform the field of medical diagnostics and material characterization, allowing for a significant reduction in radiation exposure during X-ray examinations.

X-ray imaging is an indispensable tool in various fields, including medicine and material science. To generate accurate images, high-quality detectors are essential. Current commercial detectors consist of inorganic compounds with medium to high atomic numbers. However, these materials have limitations, particularly in terms of sensitivity and stability.

The development of new bismuth-based organic-inorganic hybrid materials has addressed these limitations. Inspired by the success of halide perovskite compounds in opto-electronic devices, researchers at HZB have created two novel materials: [(CH3CH2)3S]6Bi8I30 and [(CH3CH2)3S]AgBiI5. These materials demonstrate exceptional sensitivity and stability, making them ideal for X-ray detection.

A particularly environmentally friendly manufacturing process was used to produce these materials: ball milling. This method produces polycrystalline powders that are then pressed into dense pellets. The procedures involved are also established in industry, making the production of these hybrid materials scalable and sustainable.

The novel materials were evaluated for their use in X-ray detectors, with impressive results. They show sensitivities up to two orders of magnitude higher than commercial materials like amorphous selenium or CdZnTe – and can detect X-ray doses nearly 50 times lower.

The team also studied the samples at the KMC-3 XPP beamline at BESSY II, where the detectors maintained a stable response during pulsed X-ray irradiation under high-intensity photon flux. No measurable degradation in performance was observed post-exposure, highlighting the robustness of the detector materials.

This breakthrough has significant implications for medical diagnostics and material characterization. The development of highly sensitive X-ray detectors using bismuth-based organic-inorganic hybrid materials has the potential to reduce radiation exposure during X-ray imaging. This is particularly important in medical applications, where minimizing radiation exposure is crucial.

The next step is technology transfer, with opportunities to collaborate with companies in Adlershof to optimize the development of such X-ray detectors. This collaboration will enable the translation of this scientific breakthrough into practical applications, revolutionizing the field of medical diagnostics and material characterization.

Chemistry

Scientists Stunned by Record-Breaking, Watermelon-Shaped Nucleus: Breakthrough Discovery in Nuclear Physics

Scientists in Finland have measured the heaviest known nucleus to undergo proton emission, discovering the rare isotope 188-astatine. It exhibits a unique shape and may reveal a new kind of nuclear interaction.

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Scientists have made a groundbreaking discovery in nuclear physics, measuring the heaviest nucleus ever recorded to decay via proton emission. This achievement marks the first time such a feat has been accomplished in over 30 years, with the previous record set in 1996.

The research team from the University of Jyväskylä, Finland, successfully produced and measured the lightest known isotope of astatine, 188At, consisting of 85 protons and 103 neutrons. This exotic nucleus was created through a complex process involving a fusion-evaporation reaction and identified using a sophisticated detector setup.

“The properties of this nucleus reveal a trend change in the binding energy of the valence proton,” explains Doctoral Researcher Henna Kokkonen, who led the study. “This could be explained by an interaction unprecedented in heavy nuclei.”

The research team’s findings have significant implications for our understanding of atomic nuclei and their behavior. By expanding a theoretical model to interpret the measured data, scientists can now better comprehend the intricate mechanisms governing these complex systems.

Kokkonen notes that studying such exotic nuclei is extremely challenging due to their short lifetimes and low production cross sections. However, precise techniques like those employed in this study have made it possible to unlock new insights into the fundamental nature of matter.

The research article was published in Nature Communications as part of an international collaboration involving experts in theoretical nuclear physics. This breakthrough discovery not only pushes the boundaries of human knowledge but also has far-reaching implications for our understanding of the universe and its mysteries.

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Chemistry

From Lead to Gold in a Fraction of a Second at the Large Hadron Collider

At the Large Hadron Collider, scientists from the University of Kansas achieved a fleeting form of modern-day alchemy — turning lead into gold for just a fraction of a second. Using ultra-peripheral collisions, where ions nearly miss but interact through powerful photon exchanges, they managed to knock protons out of nuclei, creating new, short-lived elements. This breakthrough not only grabbed global attention but could help design safer, more advanced particle accelerators of the future.

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The Large Hadron Collider (LHC), a 17-mile particle accelerator buried under the French-Swiss border, has achieved the centuries-old dream of alchemists: transforming lead into gold. However, this accomplishment was not without its limitations – it happened within a fraction of a second. The scientists reported their results in Physical Reviews.

The achievement was made possible by the sophisticated and sensitive detector called ALICE, which is roughly the size of a McMansion. It was scientists from the University of Kansas, working on the ALICE experiment, who developed the technique that tracked “ultra-peripheral” collisions between protons and ions that resulted in gold creation at the LHC.

According to Daniel Tapia Takaki, professor of physics and leader of KU’s group at ALICE, these ultra-peripheral collisions involve near misses between particles. The ions racing around the LHC tunnel are heavy nuclei with many protons, each generating powerful electric fields. When accelerated, these charged ions emit photons – they shine light.

“When you accelerate an electric charge to near light speeds, it starts shining,” Tapia Takaki said. “One ion can shine light that essentially takes a picture of the other. When that light is energetic enough, it can probe deep inside the other nucleus, like a high-energy flashbulb.”

During these ultra-peripheral collisions, surprising interactions can occur, including the creation of gold through photon-photon collisions. These events are incredibly clean, with almost nothing else produced. They contrast with typical collisions where sprays of particles flying everywhere.

However, the ALICE detector and the LHC were designed to collect data on head-on collisions that result in messy sprays of particles. These clean interactions were hard to detect with earlier setups.

Tapia Takaki’s KU co-authors on the paper are graduate student Anna Binoy; graduate student Amrit Gautam; postdoctoral researcher Tommaso Isidori; postdoctoral research assistant Anisa Khatun; and research scientist Nicola Minafra. The KU team at the LHC ALICE experiment plans to continue studying the ultra-peripheral collisions.

Tapia Takaki said that while the creation of gold fascinated the public, the potential of understanding the interactions goes deeper. This light is so energetic, it can knock protons out of the nucleus, sometimes one, sometimes two, three or even four protons. We can see these ejected protons directly with our detectors.

Each proton removed changes the elements: One gives thallium, two gives mercury, three gives gold. These new nuclei are very short-lived, they decay quickly, but not always immediately. Sometimes they travel along the beamline and hit parts of the collider – triggering safety systems.

That’s why this research matters beyond the headlines. With proposals for future colliders even larger than the LHC – some up to 100 kilometers in Europe and China – you need to understand these nuclear byproducts. This ‘alchemy’ may be crucial for designing the next generation of machines.

This work was supported by the U.S. Department of Energy Office of Science, Office of Nuclear Physics.

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Cosmic Rays

The Nuclear Clock That Could Unmask Dark Matter

Physicists are exploring thorium-229’s unique properties to create a nuclear clock so precise it could detect the faintest hints of dark matter. Recent measurement advances may allow scientists to spot tiny shifts in the element’s resonance spectrum, potentially revealing the nature of this mysterious substance.

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The search for dark matter has been ongoing for nearly a century, with scientists trying various methods to detect this invisible substance. Despite numerous attempts, very little is known about its fundamental properties. However, researchers believe that if a nuclear clock is developed, it could finally unmask dark matter’s influence on visible matter.

Physicists in Germany and Colorado made a breakthrough last year by using the radioactive element thorium-229 to build a potential nuclear clock. When Prof. Gilad Perez’s theoretical physics group at the Weizmann Institute of Science learned of this achievement, they recognized an opportunity to advance the search for dark matter even before a fully functional nuclear clock becomes a reality.

The team proposed a novel method for detecting dark matter’s influence on properties of the thorium-229 nucleus. They hypothesized that minute deviations in the absorption spectrum of thorium-229 could reveal dark matter’s effect, allowing them to study its properties.

Calculations showed that the new measurements could detect dark matter’s influence even if it were 100 million times weaker than gravity. The researchers also calculated how different dark matter models would affect thorium-229’s absorption spectrum, hoping this will ultimately help determine which models are accurate and what dark matter is actually made of.

While laboratories around the world continue to refine the measurement of thorium-229’s resonance frequency, a process expected to take years, the development of a nuclear clock could revolutionize many fields, including Earth and space navigation, communications, power grid management, and scientific research.

A thorium-229-based nuclear clock would be the ultimate detector for dark matter, enabling researchers to detect incredibly slight deviations in its ticking, which could reveal dark matter’s influence. The European Research Council (ERC) recently awarded an ERC Advanced Grant to Prof. Perez’s group to support the continued development of this line of research.

In conclusion, the search for dark matter continues, and a nuclear clock may finally unmask its influence on visible matter. While the journey ahead will be long and challenging, researchers remain hopeful that their efforts will ultimately reveal the secrets of this mysterious substance.

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