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Chemistry

“Nature’s Filter: Plant-Based Extracts Show Promise in Removing Microplastics from Water”

The substances behind the slimy strings from okra and the gel from fenugreek seeds could trap microplastics better than a commonly used synthetic polymer. Previously, researchers proposed using these sticky natural polymers to clean up water. Now, they report that okra and/or fenugreek extracts attracted and removed up to 90% of microplastics in ocean water, freshwater and groundwater.

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The fight against microplastic pollution has taken a promising turn. Researchers have discovered that extracts from plants like okra and fenugreek can trap and remove up to 90% of these tiny plastic particles from various types of water – ocean, freshwater, and groundwater. This breakthrough, published in ACS Omega, offers a biodegradable and non-toxic alternative to synthetic polymers currently used for wastewater treatment.

Researchers led by Rajani Srinivasan have been exploring plant-based approaches to clean contaminated water. In lab experiments, they found that extracts from okra, fenugreek, and tamarind formed sticky natural polymers that clump together with microplastics, making it easy to separate them from the water. The team demonstrated successful removals in freshwater and ocean water at a meeting of the American Chemical Society.

To extract these sticky plant polymers, researchers soaked sliced okra pods and blended fenugreek seeds in water overnight. They then removed the dissolved extracts, dried them into powders, and analyzed their composition. Initial tests showed that the powdered extracts contained polysaccharides, natural polymers capable of attracting microplastics.

The researchers then tested these plant extracts on real-world samples from waterbodies around Texas. The results varied depending on the original water source: okra worked best in ocean water (80%), fenugreek in groundwater (80-90%), and a combination of both in freshwater (77%). The team hypothesizes that this difference is due to the varying types, sizes, and shapes of microplastics present in each water sample.

Currently, polyacrylamide is used for contaminant removal during wastewater treatment. However, the researchers propose using okra and fenugreek extracts as biodegradable and non-toxic alternatives.

“Utilizing these plant-based extracts in water treatment will remove microplastics and other pollutants without introducing additional toxic substances to the treated water,” says Srinivasan. “This can significantly reduce long-term health risks to the population.”

The researchers acknowledge funding from various institutions, including the U.S. Department of Energy, Tarleton State University, and the National Science Foundation Research Experiences for Undergraduates program.

Chemistry

Scientists Confirm a Fundamental Quantum Rule for the First Time

Scientists have, for the first time, experimentally proven that angular momentum is conserved even when a single photon splits into two, pushing quantum physics to its most fundamental limits. Using ultra-precise equipment, the team captured this elusive process—comparable to finding a needle in a haystack—confirming a cornerstone law of nature at the photon level.

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Scientists at Tampere University and their international collaborators have made a groundbreaking discovery in the field of quantum physics. They have experimentally confirmed that angular momentum is conserved when a single photon is converted into a pair, validating a key principle of physics at the quantum level for the first time. This breakthrough has significant implications for creating complex quantum states useful in computing, communication, and sensing.

In essence, the researchers have tested the conservation laws of rotating objects to see if they also apply to light. They found that when a photon with zero orbital angular momentum is split into two photons, the OAM quanta of both photons must add to zero. This means that if one of the newly generated photons has one OAM quanta, its partner photon must have the opposite, i.e., negative OAM quanta.

The researchers used an extremely stable optical setup and delicate measurements to record enough successful conversions such that they could confirm the fundamental conservation law. They also observed first indications of quantum entanglement in the generated photon pairs, which suggests that the technique can be extended to create more complex photonic quantum states.

This work is not only of fundamental importance but also takes us a significant step closer to generating novel quantum states, where the photons are entangled in all possible ways. The researchers plan to improve the overall efficiency of their scheme and develop better strategies for measuring the generated quantum state such that in the future these photonic needles can be found easier in the laboratory haystack.

The confirmation of this fundamental quantum rule opens new possibilities for creating complex quantum states useful in computing, communication, and sensing. It also takes us a significant step closer to generating novel quantum states, where the photons are entangled in all possible ways, i.e., in space, time, and polarization.

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Biochemistry

Scientists Finally Tame the Impossible: A Stable 48-Atom Carbon Ring is Achieved

Researchers have synthesized a stable cyclo[48]carbon, a unique 48-carbon ring that can be studied in solution at room temperature, a feat never achieved before.

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The discovery of a new type of molecular carbon allotrope, known as cyclocarbon, has been a long-standing challenge for chemists. A team of researchers from Oxford University’s Department of Chemistry, led by Dr Yueze Gao and senior author Professor Harry Andersen, have successfully synthesized a stable 48-atom carbon ring in solution at room temperature. This achievement marks a significant breakthrough in the field, as previous attempts to study cyclocarbons were limited to the gas phase or extremely low temperatures (4 to 10 K).

The researchers employed a unique approach by synthesizing a cyclocarbon catenane, where the C48 ring is threaded through three other macrocycles. This design increases the stability of the molecule, preventing access to the sensitive cyclocarbon core. The team developed mild reaction conditions for the unmasking step in the synthesis process, which allowed them to achieve a stable cyclocarbon in solution at 20°C.

The cyclocarbon catenane was characterized using various spectroscopic techniques, including mass spectrometry, NMR, UV-visible, and Raman spectroscopy. The observation of a single intense 13C NMR resonance for all 48 sp1 carbon atoms provides strong evidence for the cyclocarbon catenane structure.

Lead author Dr Yueze Gao stated that achieving stable cyclocarbons in a vial at ambient conditions is a fundamental step, making it easier to study their reactivity and properties under normal laboratory conditions. Senior author Professor Harry Andersen added that this achievement marks the culmination of a long endeavor, with the original grant proposal written in 2016 based on preliminary results from 2012-2015.

The study also involved researchers from the University of Manchester, the University of Bristol, and the Central Laser Facility, Rutherford Appleton Laboratory. This collaborative effort demonstrates the power of interdisciplinary research in advancing our understanding of complex molecular systems.

This achievement has significant implications for future studies on cyclocarbons and their potential applications in various fields. The researchers’ innovative approach to synthesizing stable cyclocarbons at room temperature opens up new possibilities for exploring the properties and reactivity of these intriguing molecules.

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Chemistry

Scientists Stunned by Record-Breaking, Watermelon-Shaped Nucleus: Breakthrough Discovery in Nuclear Physics

Scientists in Finland have measured the heaviest known nucleus to undergo proton emission, discovering the rare isotope 188-astatine. It exhibits a unique shape and may reveal a new kind of nuclear interaction.

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Scientists have made a groundbreaking discovery in nuclear physics, measuring the heaviest nucleus ever recorded to decay via proton emission. This achievement marks the first time such a feat has been accomplished in over 30 years, with the previous record set in 1996.

The research team from the University of Jyväskylä, Finland, successfully produced and measured the lightest known isotope of astatine, 188At, consisting of 85 protons and 103 neutrons. This exotic nucleus was created through a complex process involving a fusion-evaporation reaction and identified using a sophisticated detector setup.

“The properties of this nucleus reveal a trend change in the binding energy of the valence proton,” explains Doctoral Researcher Henna Kokkonen, who led the study. “This could be explained by an interaction unprecedented in heavy nuclei.”

The research team’s findings have significant implications for our understanding of atomic nuclei and their behavior. By expanding a theoretical model to interpret the measured data, scientists can now better comprehend the intricate mechanisms governing these complex systems.

Kokkonen notes that studying such exotic nuclei is extremely challenging due to their short lifetimes and low production cross sections. However, precise techniques like those employed in this study have made it possible to unlock new insights into the fundamental nature of matter.

The research article was published in Nature Communications as part of an international collaboration involving experts in theoretical nuclear physics. This breakthrough discovery not only pushes the boundaries of human knowledge but also has far-reaching implications for our understanding of the universe and its mysteries.

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